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Occurrences: Sam can force a demon to leave its host through sheer force of will.
Initially, using this ability caused Sam a great deal of stress and would often result in severe headaches and nosebleeds, but with time and practice he was able to exorcise a demon without these side-effects.
Sam cannot control when the premonitions occur or what they're about, and they are often accompanied by intense headaches.
Sam and Dean theorize that Sam only has premonitions when they are somehow related to the Yellow-Eyed Demon.
This is likely true, for Sam ceases to experience visions after the demon's death in 2.22 All Hell Breaks Loose: Part Two, which also suggests that his visions were a result of some sort of link between himself and YED.
Demon, Sam eventually reaches a point where no demon can harm him so long as he's high on demon blood.Occurrences: Sam has immunities to demonic attacks that steadily expand over time.At first, Sam was vulnerable to all forms of demon powers, being easily overpowered by telekinesis from both YED and lesser demons.However, his first bout of immunity manifests after being exposed to the Croatoan virus.Sam proves immune, and is later able to survive Lilith's "light" without any harm.
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By the time he wields his power again, Sam is shown to be highly adept at hurling a demon as powerful as Alastair across a graveyard with little effort.